Specifies a device of 32 (0x20) and a Subdevice of 222 (0xDE)
Which is why the codes you generated don't work.
You'd need to generate codes using the device and subdevice of a command that works. i.e. A Device of 1 (0x01) and a Subdevice or 253 (0xFD).
I presume you are trying to use Pronto Codes for a Yamaha Receiver?
If so, there are packaged files in the Classic Pronto Files section for Yamaha RXV1, RXV900 that contain Excel sheets for most of the extended codes for a Yamaha receiver.