Haven't tried it on the Neo. With other learning remotes if, when learning to a button, you push the Action button with the IR window covered, then push the HD/SD button with the IR window uncovered, you'll capture the first command (HD or SD, depending on where you started). Repeat the process learning to another button, and you'll capture the second command.
This should work fine with the Neo.
Mike
www.surfremote.com