For this one you don't need a cable. On your URC-8820N, assign setup code 1360 to Audio, and then assign Main On = 01956 to some button. Main Off is 01982.
Once setup code 1360 is assigned
1) Press Setup until 2 blinks
2) Enter 994
3) Tap Setup
4) Enter 01956
5) Press (e.g. PIP)
The remote should blink twice. Now when you press PIP, the Main On signal will be sent.
I used IrMaster to find that the Pronto Hex is Denon device 2, functions 121 and 122. The
Lookup Tool tool tells us that the URC-8820N has Denon Combo (official) protocol on Audio 1360, and I used RemoteMaster to get the corrresponding 5 digit EFCs.