AFAIK, the only Zenith discrete power commands are found on their VCR and their very newest plasma displays that use the NEC protocol.
Rob Crowe, the creator of the unofficial OneFor-All site
www.hifi-remote.com and hte JP1 group decoded the Zenith protocol a couple of years ago and the command posted is: (+ designates a One and the - a Zero)
Power:
0000 0067 0000 0013=Preamble
0014 00cf = Lead In
-0014 00cf 0014 0014 0014 00a7
+0014 0014 0014 00a7 0014 00cf
+0014 0014 0014 00a7 0014 00cf
+0014 0014 0014 00a7 0014 00cf
-0014 00cf 0014 0014 0014 00a7
-0014 00cf 0014 0014 0014 112c
Both the One and Zero use three burst pairs. There are 6-bits and only the VCR that has 7-bits has a discrete power command.
-Jon