Basically you pair the shades using the powerview app. Then you create discrete scenes such as: Master Blackout Open, Master Blackout Close, All Master Closed, All Master Open.

then you add the Powerview Hub module, and input it's ip address ( set it fixed of course )

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Then you add the Scene Modules, as many as you want.
input the EXACT name of the scene, and jam all the outputs to the input of the hub module.

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Pretty easy, the problem is that powerview SUCKS big time. the range is awful, so unreliable.